Visible‐Light Mediated Metal‐Free Cross‐Electrophile Coupling of Isatin Derivatives with Electron‐Poor Alkenes | Zendy

Maji Kakoli | Zendy; Rai Pramod | Zendy; Maji Biplab | Zendy

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Visible‐Light Mediated Metal‐Free Cross‐Electrophile Coupling of Isatin Derivatives with Electron‐Poor Alkenes

Author(s) -

Maji Kakoli,

Rai Pramod,

Maji Biplab

Publication year - 2021

Publication title -

asian journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.846

H-Index - 44

eISSN - 2193-5815

pISSN - 2193-5807

DOI - 10.1002/ajoc.202100308

Subject(s) - chemistry , electrophile , alkene , isatin , photochemistry , visible spectrum , transition metal , amine gas treating , radical , organic chemistry , catalysis , physics , optoelectronics

A transition metal‐free cross‐electrophile coupling of isatins with acceptor‐substituted alkene has been developed. The reaction operates at room temperature utilizing abundant amine as the terminal reductant under visible light irradiation. A large number of γ‐hydroxy esters and γ‐butyrolactones were synthesized in moderate to good yields tolerating a broad range of functional groups.

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