Oxidative [3+2] Annulation of Pyridinium Salts with  gem ‐Difluoroalkenes: Synthesis of 2‐Fluoroindolizines | Zendy

Yang Li–Miao | Zendy; Zhang YouYa | Zendy; Deng JingTong | Zendy; Ma AiJun | Zendy; Zhang XiangZhi | Zendy; Zhang ShuYu | Zendy; Peng JinBao | Zendy

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Oxidative [3+2] Annulation of Pyridinium Salts with gem ‐Difluoroalkenes: Synthesis of 2‐Fluoroindolizines

Author(s) -

Yang Li–Miao,

Zhang YouYa,

Deng JingTong,

Ma AiJun,

Zhang XiangZhi,

Zhang ShuYu,

Peng JinBao

Publication year - 2021

Publication title -

asian journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.846

H-Index - 44

eISSN - 2193-5815

pISSN - 2193-5807

DOI - 10.1002/ajoc.202100253

Subject(s) - pyridinium , chemistry , annulation , oxidative phosphorylation , combinatorial chemistry , pyridinium compounds , organic chemistry , base (topology) , catalysis , biochemistry , mathematical analysis , mathematics

An oxidative [3+2] annulation of pyridinium salts with gem ‐difluoroalkenes for the synthesis of highly substituted 2‐fluoroindolizines has been developed. Using DBU as base, a broad range of multisubstituted 2‐fluoroindolizines were prepared in good to excellent yields under mild conditions, and many useful functional groups can be tolerated.

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