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Thiocyanation/Cyclization of γ‐hydroxy Olefins to Access Thiocyanato‐Containing Oxygen Heterocyclic Compounds
Author(s) -
Li Chengcheng,
Long Pingliang,
Fu Zhenda,
Wu Di,
Chen FuXue,
Yin Hongquan
Publication year - 2021
Publication title -
asian journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.846
H-Index - 44
eISSN - 2193-5815
pISSN - 2193-5807
DOI - 10.1002/ajoc.202100175
Subject(s) - chemistry , furan , yield (engineering) , ring (chemistry) , oxygen , reaction conditions , functional group , combinatorial chemistry , organic chemistry , medicinal chemistry , catalysis , materials science , polymer , metallurgy
A new thiocyanation/cyclization reaction was developed to synthesize thiocyanato‐containing oxygen heterocyclic compounds with terminal and non‐terminal enols. The approach supplies an efficient method to build the multi‐substituted ring and spiro ring structure of furan, which has a wide range of substrates, good functional group tolerance, and the desired products can be obtained in a medium to high yield.