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Molybdenum‐Catalyzed Deoxygenative Cyclization of Carbonyl Compounds for the Synthesis of Pyrido[2,1‐ a ]isoindoles
Author(s) -
Asako Sobi,
Kobayashi Takafumi,
Ishihara Seina,
Takai Kazuhiko
Publication year - 2021
Publication title -
asian journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.846
H-Index - 44
eISSN - 2193-5815
pISSN - 2193-5807
DOI - 10.1002/ajoc.202100038
Subject(s) - chemistry , deoxygenation , catalysis , phosphine , molybdenum , quinone , organic chemistry , combinatorial chemistry , medicinal chemistry
Abstract A simple catalytic system consisting of Mo(0) and ortho‐quinone as catalyst and phosphine as a reductant has been developed for the synthesis of pyridoisoindoles and pyridoisoindolium salts through the deoxygenation of carbonyl compounds.