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Visible‐light‐Induced Sulfhydrylation and Oxylation of Olefins with Iodine as Catalyst
Author(s) -
Ren Ming Zhe,
Yang Ying Hui,
Zhu Zheng He,
Zhang Bo Sheng,
Quan Zheng Jun,
Wang Xi Cun
Publication year - 2021
Publication title -
asian journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.846
H-Index - 44
eISSN - 2193-5815
pISSN - 2193-5807
DOI - 10.1002/ajoc.202100012
Subject(s) - chemistry , catalysis , bifunctional , nucleophile , visible spectrum , photochemistry , iodine , diol , organic chemistry , physics , optoelectronics
Abstract Herein, the sulfhydrylation and oxylation of olefins were completed under visible light irradiation with iodine as catalyst, which realized more economical and green chemical conversion because of the absence of metal complexes or organic dyes. A series of bifunctional modifications of olefins were achieved with good yields by using diol derivatives and water as nucleophiles. In addition, the control experiments show that the reaction is a free radical process.