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CAN‐mediated Oxidative Coupling‐Reaction of Xanthenes with Enaminones
Author(s) -
Zhang Changyuan,
Qiu Yun,
Zhang Jiantao,
Chen Lulu,
Xu Shuting,
Guo Huosheng,
Luo Jian,
Tan Yao
Publication year - 2021
Publication title -
asian journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.846
H-Index - 44
eISSN - 2193-5815
pISSN - 2193-5807
DOI - 10.1002/ajoc.202000617
Subject(s) - xanthene , chemistry , yield (engineering) , double bond , oxidative phosphorylation , functional group , coupling reaction , combinatorial chemistry , photochemistry , oxygen , organic chemistry , catalysis , biochemistry , materials science , metallurgy , polymer
An efficient CAN‐mediated C−C bond formation in the oxidative reactions of xanthenes with enaminones under mild reaction conditions are described. A variety of 9H‐xanthene‐9‐ylidene aldehydes could be synthesized in up to 90% yield via one‐pot manner with good functional group compatibility, which achieved the simultaneous construction of carbon‐carbon double bond and carbon‐oxygen double bond.