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Effect of Azobenzene Regioisomerism on Intrinsically Curved Supramolecular Polymers
Author(s) -
Tamaki Kenta,
Datta Sougata,
Tashiro Keigo,
Isobe Atsushi,
Silly Fabien,
Yagai Shiki
Publication year - 2021
Publication title -
asian journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.846
H-Index - 44
eISSN - 2193-5815
pISSN - 2193-5807
DOI - 10.1002/ajoc.202000535
Subject(s) - azobenzene , photoisomerization , supramolecular chemistry , chemistry , polymer , supramolecular polymers , polymerization , polymer chemistry , solvent , photochemistry , crystallography , molecule , isomerization , organic chemistry , catalysis
Supramolecular polymerization of two regioisomeric naphthalene‐azobenzene dyads bearing barbituric acid and tri(dodecyloxy)phenyl units were studied in nonpolar solvent. Supramolecular polymers of the two compounds differ considerably in their topologies. While the isomer of which azobenzene unit was introduced along to its longer molecular axis formed randomly coiled supramolecular polymers with intrinsic curvature, the other of which azobenzene unit was introduced along to its shorter molecular axis formed linearly extended supramolecular polymers. Furthermore, due to their different degrees of geometrical changes accompanied with photoisomerization of the azobenzene unit, only the former showed a large topological change upon photo‐irradiation. The different structural and photoresponsive properties can be attributed to the distinct geometries of supermacrocyclic hydrogen‐bonded intermediates (rosettes).