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Recent Progress in the C−N Bond Formation via High‐Valent Group 9 Cp*M(III)‐Catalyzed Directed sp 2 C−H Activation
Author(s) -
Sk Md Raja,
Bera Sourav Sekhar,
Basuli Suchand,
Metya Abhisek,
Maji Modhu Sudan
Publication year - 2020
Publication title -
asian journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.846
H-Index - 44
eISSN - 2193-5815
pISSN - 2193-5807
DOI - 10.1002/ajoc.202000367
Subject(s) - chemistry , catalysis , rhodium , iridium , transition metal , cobalt , context (archaeology) , metal , group (periodic table) , medicinal chemistry , stereochemistry , inorganic chemistry , organic chemistry , paleontology , biology
The presence of nitrogen atom in a wide variety of organic compounds called for the use of powerful C−H activation strategy in the C−N bond formation. Pentamethylcyclopentadienyl (Cp*) based, high‐valent, group 9 transition‐metal complexes have shown a great potential as catalysts in the C−H activation/functionalization over the years. This minireview summarizes recent progress made in the context of C−N bond formation via catalytic (sp 2 )C−H activation with Cp*M(III) (M=Co, Rh and Ir) catalysts. A general plausible mechanism is briefly discussed at the beginning, and then results are arranged according to metal cobalt, rhodium and iridium, respectively.