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Cooperative Application of Conventional and Microwave Heating
Author(s) -
Fulo Harvey F.,
Vincent Morgan A.,
Stiegman Albert E.,
Dudley Gregory B.
Publication year - 2020
Publication title -
asian journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.846
H-Index - 44
eISSN - 2193-5815
pISSN - 2193-5807
DOI - 10.1002/ajoc.202000157
Subject(s) - microwave heating , microwave , chemistry , dielectric heating , reagent , heating system , microwave chemistry , ionic bonding , process engineering , nanotechnology , chemical physics , microwave irradiation , organic chemistry , thermodynamics , catalysis , ion , materials science , telecommunications , computer science , physics , engineering
The coordinated, cooperative use of microwave heating with conventional heating can provide advantages in chemical synthesis. Here, heterogeneous mixtures comprising ionic, highly microwave‐absorbing organic reagents and nearly microwave‐transparent arene solvents are heated conventionally and/or with microwaves, resulting in faster and, in some cases, higher yielding reactions when the two heating methods are applied cooperatively as compared to either method independently. Control experiments in more polar arene solvents show no advantage of cooperative heating, consistent with selective microwave heating phenomena. The experiments are facilitated by reactor technology that regulates internal reaction temperature and coordinates the application of conventional and microwave heating. The positive outcomes in this initial exploratory system suggest that cooperative heating can offer benefits in other systems designed for selective microwave heating.