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Chiral Tetraarylmethane Derivative with Metal‐Coordinating Ability
Author(s) -
Matsumoto Kouzou,
Miki Kaori,
Tanaka Rina,
Matsuda Takahiro,
Nehira Tatsuo,
Hirao Yasukazu,
Kurata Hiroyuki,
Pescitelli Gennaro,
Kubo Takashi
Publication year - 2020
Publication title -
asian journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.846
H-Index - 44
eISSN - 2193-5815
pISSN - 2193-5807
DOI - 10.1002/ajoc.202000132
Subject(s) - chemistry , nitrogen atom , carbon atom , derivative (finance) , aryl , atom (system on chip) , metal , spectral line , metal ions in aqueous solution , solvent , ion , asymmetric carbon , nitrogen , carbon fibers , crystallography , stereochemistry , organic chemistry , optically active , ring (chemistry) , alkyl , physics , materials science , astronomy , composite number , computer science , financial economics , economics , composite material , embedded system
The synthesis of a chiral tetraarylmethane derivative is reported. The solvent effect on the CD spectra was observed for the solution. This is attributable to a molecular design with three of four aryl groups have the nitrogen atom at the ortho position with respect to the central carbon atom. This unique design was realized when a variety of transition metal ions were added to the solution, showing different patterns of CD spectra. This cover picture is a personified translation of this experimental observation. The cartoon also implies a law of human nature: two pupils reacting differently to one thing. More information can be found in the Full Paper by Kouzou Matsumoto, Tatsuo Nehira et al.