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Rhodium‐Catalyzed Synthesis of Heteroarylselenyl Esters from Diheteroaryl Diselenides and Acid Fluorides
Author(s) -
Arisawa Mieko,
Suzuki Ren,
Ohashi Keiichiro,
Yamaguchi Masahiko
Publication year - 2020
Publication title -
asian journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.846
H-Index - 44
eISSN - 2193-5815
pISSN - 2193-5807
DOI - 10.1002/ajoc.202000077
Subject(s) - chemistry , rhodium , catalysis , reagent , triphenylphosphine , organic chemistry , platinum , medicinal chemistry , combinatorial chemistry
A rhodium complex catalyzed C−Se bond formation between diheteroaryl diselenides and acid fluorides in the presence of triphenylphosphine to provide heteroarylselenyl esters in good yields. The reaction was applicable to five‐ and six‐membered heteroaryl compounds. The heteroarylselenyl esters can be used as heteroaryselenating reagents in the synthesis of heteroaryl selenides, as shown by a platinum‐catalyzed addition reaction with 1‐octyne.