Cationic Iron(III) Salt as an Initiator for Radical Cation‐induced [4+2] Cycloaddition | Zendy

Horibe Takahiro | Zendy; Ohmura Shuhei | Zendy; Katagiri Kei | Zendy; Ishihara Kazuaki | Zendy

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Cationic Iron(III) Salt as an Initiator for Radical Cation‐induced [4+2] Cycloaddition

Author(s) -

Horibe Takahiro,

Ohmura Shuhei,

Katagiri Kei,

Ishihara Kazuaki

Publication year - 2020

Publication title -

asian journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.846

H-Index - 44

eISSN - 2193-5815

pISSN - 2193-5807

DOI - 10.1002/ajoc.201900749

Subject(s) - chemistry , cationic polymerization , cycloaddition , salt (chemistry) , radical ion , radical , medicinal chemistry , photochemistry , polymer chemistry , combinatorial chemistry , organic chemistry , catalysis , ion

We developed a cationic iron(III) salt initiator for radical cation‐induced [4+2] cycloaddition. Fe(OTf) 3 [or Fe(ClO 4 ) 3 ] behaves as a highly active oxidant for both electron‐deficient and electron‐rich dienophiles. The scope of substrates is much broader than with FeCl 3 reported previously. With highly active Fe(OTf) 3 , we demonstrate a formal total synthesis of Heitziamide A.

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