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Photocatalytic Synthesis of Diphosphorous Quinoline Compounds
Author(s) -
Xiong Yunkui,
Zhang Yu,
Qi Liping,
Jiang Minbao,
Zhang Jianye,
Wang Tao
Publication year - 2020
Publication title -
asian journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.846
H-Index - 44
eISSN - 2193-5815
pISSN - 2193-5807
DOI - 10.1002/ajoc.201900717
Subject(s) - quinoline , chemistry , photocatalysis , environmentally friendly , catalysis , surface modification , diphenylphosphine oxide , combinatorial chemistry , phosphate , green chemistry , diphenylphosphine , organic chemistry , reaction mechanism , phosphine , ecology , biology
Herein, we report the reaction of quinoline with diphenylphosphine oxide in the presence of visible light without catalyst. The reaction completes in 24 h under the mild conditions and the substrates are well tolerant. This method provides a straightforward and environmentally friendly access to diphosphorous quinoline compounds. Similarly, this method can also aid in the phosphate functionalization of some heterocyclic compounds.