Electrochemical Oxidative C−H Sulfonylation of Anilines | Zendy

Lu Fangling | Zendy; Li Jun | Zendy; Wang Tao | Zendy; Li Zhen | Zendy; Jiang Minbao | Zendy; Hu Xingxing | Zendy; Pei Hongqiao | Zendy; Yuan Feng | Zendy; Lu Lijun | Zendy; Lei Aiwen | Zendy

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Electrochemical Oxidative C−H Sulfonylation of Anilines

Author(s) -

Lu Fangling,

Li Jun,

Wang Tao,

Li Zhen,

Jiang Minbao,

Hu Xingxing,

Pei Hongqiao,

Yuan Feng,

Lu Lijun,

Lei Aiwen

Publication year - 2019

Publication title -

asian journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.846

H-Index - 44

eISSN - 2193-5815

pISSN - 2193-5807

DOI - 10.1002/ajoc.201900447

Subject(s) - chemistry , electrochemistry , yield (engineering) , oxidative phosphorylation , oxidative coupling of methane , catalysis , combinatorial chemistry , sodium , organic chemistry , electrode , biochemistry , materials science , metallurgy

An electrochemical oxidative C−H sulfonylation of anilines without a metal catalyst and an external oxidant has been developed. Various sodium sulfinates are compatible, generating the desired products in up to 96% yield. Preliminary mechanism studies suggest that a radical cross‐coupling process is involved in this transformation.

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