1,3,5‐Triphenylpyrazoline‐Based Organocatalysis: Synthesis of Aryl‐Heteroaryl Compounds and Exploiting By‐Product from the Reaction for Alkyne‐Carbonyl Metathesis (ACM) Reaction in One Pot | Zendy

Annes Sesuraj Babiola | Zendy; Ramesh Subburethinam | Zendy

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1,3,5‐Triphenylpyrazoline‐Based Organocatalysis: Synthesis of Aryl‐Heteroaryl Compounds and Exploiting By‐Product from the Reaction for Alkyne‐Carbonyl Metathesis (ACM) Reaction in One Pot

Author(s) -

Annes Sesuraj Babiola,

Ramesh Subburethinam

Publication year - 2019

Publication title -

asian journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.846

H-Index - 44

eISSN - 2193-5815

pISSN - 2193-5807

DOI - 10.1002/ajoc.201900305

Subject(s) - chemistry , organocatalysis , alkyne , aryl , metathesis , combinatorial chemistry , catalysis , salt metathesis reaction , organic chemistry , enantioselective synthesis , alkyl , polymer , polymerization

A pyrazoline‐based organocatalyst was synthesized and used for the sequential formation of two structurally important heterocyclic compounds in one pot. A variety of substrates were found to be suitable for both arylation and alkyne‐carbonyl metathesis (ACM) reactions. Control reactions were performed to understand the catalytic pathway and a suitable mechanism was proposed.

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