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Metal‐Free Oxidation of Trichloroacetimidates to Aldehydes
Author(s) -
Lou JiCong,
Li JianYe,
Sun WenWu,
Wu Bin
Publication year - 2019
Publication title -
asian journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.846
H-Index - 44
eISSN - 2193-5815
pISSN - 2193-5807
DOI - 10.1002/ajoc.201800683
Subject(s) - chemistry , metal , organic chemistry , nuclear magnetic resonance spectroscopy
A metal‐free oxidation reaction of trichloroacetimidates to aldehydes or ketones with DMSO as an oxidant is reported. The reaction exhibits a broad range of functional group tolerance. Detailed mechanistic studies were performed with the aid of NMR, in situ IR spectroscopy, GC‐MS analysis and 18 O‐labeling experiments.