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Cover Feature: Deprotonative Generation of Cyclohexynes from Cyclic Enol Triflates Using Aluminate Bases (Asian J. Org. Chem. 7/2018)
Author(s) -
Hioki Yuto,
Yukioka Taro,
Okano Kentaro,
Mori Atsunori
Publication year - 2018
Publication title -
asian journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.846
H-Index - 44
eISSN - 2193-5815
pISSN - 2193-5807
DOI - 10.1002/ajoc.201800353
Subject(s) - chemistry , enol , aluminate , lithium (medication) , cover (algebra) , molecule , deprotonation , base (topology) , organic molecules , organic chemistry , catalysis , ion , mechanical engineering , cement , engineering , medicine , mathematical analysis , mathematics , archaeology , history , endocrinology
Strained molecules : Cyclohexynes, short‐lived strained molecules, are generated from cyclic enol triflates via deprotonation with lithium triisobutyl(2,2,6,6‐tetramethylpiperidino)aluminate as a mild base. This method provides direct access to cyclohexynes from the cyclic enol triflates, which are readily available from their corresponding cyclohexanones. More information can be found in the Communication by Kentaro Okano et al. on page 1298 in Issue 7, 2018 (DOI: 10.1002/ajoc.201800205).