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Silver‐Catalyzed Decarboxylative Trifluoromethylthiolation of Cinnamic Acids: An Easy Access to α‐Trifluoromethylthiolated Ketones
Author(s) -
Sharma Anup Kumar,
Yadav Arvind Kumar,
Singh Krishnd
Publication year - 2018
Publication title -
asian journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.846
H-Index - 44
eISSN - 2193-5815
pISSN - 2193-5807
DOI - 10.1002/ajoc.201800327
Subject(s) - chemistry , reagent , catalysis , decarboxylation , cinnamic acid , organic chemistry , in situ , combinatorial chemistry
A silver‐catalyzed decarboxylative difunctionalization of cinnamic acids has been developed to afford a variety of α‐trifluoromethylthiolated ketones under mild reaction conditions using in situ generated SCF 3 source by the combination of Langlois’ reagent and CS 2 .