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Iron‐Catalyzed Synthesis of Amines and Thioethers Directly from Allylic Alcohols
Author(s) -
Wang DanYang,
Peng XiaoMin,
Wang GuangZhu,
Zhang YaJuan,
Guo Tao,
Zhang PanKe
Publication year - 2018
Publication title -
asian journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.846
H-Index - 44
eISSN - 2193-5815
pISSN - 2193-5807
DOI - 10.1002/ajoc.201800083
Subject(s) - allylic rearrangement , chemistry , amine gas treating , catalysis , yield (engineering) , thioester , ligand (biochemistry) , organic chemistry , selectivity , combinatorial chemistry , receptor , biochemistry , materials science , metallurgy , enzyme
A straightforward and efficient approach for the synthesis of allylic amines and thioethers has been developed by an iron‐catalyzed cross‐coupling reaction using diphosphite ligand. The reaction between allylic alcohols and amines/thiols gave allylic amine and thioester. The method is compatible with various functional groups, affording products with high yield and monoallylation selectivity.