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Nickel and Copper‐Catalyzed Carbonylation Reaction of Organoboranes
Author(s) -
EtemadiDavan Elham,
Iranpoor Nasser,
Arshad Pourya
Publication year - 2018
Publication title -
asian journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.846
H-Index - 44
eISSN - 2193-5815
pISSN - 2193-5807
DOI - 10.1002/ajoc.201700681
Subject(s) - chemistry , carbonylation , catalysis , amide , nickel , copper , organic chemistry , medicinal chemistry , polymer chemistry , carbon monoxide
Carbonylation of arylboronic acid derivatives employing Cr(CO) 6 as the carbonyl source and NiCl 2 (dmg)/4,4′‐bipy as the catalyst under air without applying external oxidant has been reported for the amide and ester synthesis (dmg=dimethylgloxime; bipy=bipyridine). Moreover, CHCl 3 was also used as another carbonyl source for the amide synthesis with CuI/1,10‐phenanthroline catalytic system.