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Synthesis and Chemical Transformations of Fluorosulfates
Author(s) -
Revathi Lekkala,
Ravindar Lekkala,
Leng Jing,
Rakesh Kadalipura Puttaswamy,
Qin HuaLi
Publication year - 2018
Publication title -
asian journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.846
H-Index - 44
eISSN - 2193-5815
pISSN - 2193-5807
DOI - 10.1002/ajoc.201700591
Subject(s) - chemistry , sulfuryl chloride , organic chemistry , carbonylation , electrophile , fluoride , amination , phenol , halide , organic synthesis , sulfur , catalysis , inorganic chemistry , carbon monoxide
Fluorosulfates are readily available electrophiles that can be prepared from the reactions of phenol or alcohol derivatives with sulfuryl fluoride, fluorosulfonic acid, sulfuryl chloride fluoride, and fluorosulfonic anhydride. This Focus Review covers most of the synthetic strategies that have been reported for the construction of fluorosulfates, as well as their application as versatile building blocks in a variety of synthetic transformations, such as catalyzed amination, cross‐coupling, sulfur(VI) fluoride exchange, carbonylation, hydrolysis, alcoholysis, and as alternatives to organic halides or triflates in organic chemistry.