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D–π–A Dyes that Contain New Hydantoin Anchoring Groups for Dye‐Sensitized Solar Cells
Author(s) -
Masui Hisashi,
Maitani Masato M.,
Fuse Shinichiro,
Yamamura Ayaka,
Ogomi Yuhei,
Hayase Shuzi,
Kaiho Tatsuo,
Tanaka Hiroshi,
Wada Yuji,
Takahashi Takashi
Publication year - 2018
Publication title -
asian journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.846
H-Index - 44
eISSN - 2193-5815
pISSN - 2193-5807
DOI - 10.1002/ajoc.201700542
Subject(s) - dye sensitized solar cell , chemistry , hydantoin , photochemistry , electrochemistry , anchoring , solar cell , organic chemistry , electrode , physics , optoelectronics , electrolyte , structural engineering , engineering
The development of new anchoring groups is important to facilitate effective co‐sensitization in dye‐sensitized solar cells (DSSCs). Herein, stable organic D–π–A dyes that contain new heterocyclic hydantoin‐based anchoring groups have been designed, synthesized, and used in DSSCs. These dye sensitizers were evaluated in terms of their absorption spectra, electrochemical properties, and performance in DSSC devices. Although only one‐third of the amount of hydantoin‐containing dyes adsorbed onto TiO 2 relative to their cyanoacrylic‐acid‐containing analogues, they exhibited effective photoexcited electron‐transfer properties. External quantum efficiencies of over 80 % was observed, which were comparable to those of the cyanoacrylic‐acid‐containing dyes. In addition, the new hydantoin‐containing dyes exhibited significant robustness, which could allow improved stability of their corresponding photovoltaic devices under harsh conditions, such as high temperature and humidity.