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Copper‐Catalyzed Carboxylation of Aryl‐ and Alkenyltrialkoxysilanes
Author(s) -
Nguyen Thanh V. Q.,
Yoo WooJin,
Kobayashi Shū
Publication year - 2018
Publication title -
asian journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.846
H-Index - 44
eISSN - 2193-5815
pISSN - 2193-5807
DOI - 10.1002/ajoc.201700519
Subject(s) - carboxylation , chemistry , aryl , catalysis , copper , organic chemistry , salt (chemistry) , activator (genetics) , atmospheric pressure , carboxylic acid , biochemistry , alkyl , oceanography , gene , geology
The use of a simple copper salt as a catalyst, in conjunction with CsF as an activator, enabled a wide range of aryl‐ and alkenyltrialkoxysilanes to undergo carboxylation under atmospheric pressure of CO 2 , affording the corresponding carboxylic acids in good to high yields.