Unexpected One‐Pot Synthesis of Diindolotriazatruxene: A Planar Electron‐Rich Scaffold Toward Highly π‐Extended PAHs | Zendy

Li Xiangchun | Zendy; Wang Chunyu | Zendy; Xue Yibo | Zendy; Meng Cheng | Zendy; Lai WenYong | Zendy; Huang Wei | Zendy

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Unexpected One‐Pot Synthesis of Diindolotriazatruxene: A Planar Electron‐Rich Scaffold Toward Highly π‐Extended PAHs

Author(s) -

Li Xiangchun,

Wang Chunyu,

Xue Yibo,

Meng Cheng,

Lai WenYong,

Huang Wei

Publication year - 2017

Publication title -

asian journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.846

H-Index - 44

eISSN - 2193-5815

pISSN - 2193-5807

DOI - 10.1002/ajoc.201700498

Subject(s) - chemistry , planar , scaffold , mass spectrometry , electrochemistry , block (permutation group theory) , crystal structure , chemical engineering , combinatorial chemistry , nanotechnology , crystallography , materials science , electrode , medicine , computer graphics (images) , geometry , mathematics , chromatography , computer science , biomedical engineering , engineering

A unique planar and highly π‐extended scaffold, 3,8,14,19‐tetrabromo‐diindolotriazatruxene ( 4Br‐DIT ), was synthesized via a facile one‐pot strategy. The structure of 4Br‐DIT was adequately verified by MALDI‐TOF mass spectrometry, 1 H and 13 C NMR, and single‐crystal XRD analysis. A combination of thermal, optical, and electrochemical investigation confirmed the electron‐rich characteristics of the resulting diindolotriazatruxene unit, showing promise as a building block to construct highly π‐extended polycyclic aromatic hydrocarbons (PAHs).

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