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Synthesis of Indenes that are Derived from Aldimines with Enones Under Rhodium(III) Catalysis
Author(s) -
Han Sang Hoon,
Kim Saegun,
Mishra Neeraj Kumar,
Oh Hyunjung,
Choi Myung Hoon,
Choi Dong Seok,
Lim Hyeon Ju,
Shin Dong Yeop,
Kim In Su
Publication year - 2017
Publication title -
asian journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.846
H-Index - 44
eISSN - 2193-5815
pISSN - 2193-5807
DOI - 10.1002/ajoc.201700473
Subject(s) - aldimine , chemistry , rhodium , indene , intramolecular force , catalysis , alkylation , selectivity , organic chemistry , medicinal chemistry , stereochemistry
The rhodium(III)‐catalyzed C−H alkylation and intramolecular cyclization of aldimines with enones are described. This transformation provides direct access to the formation of C2‐carbonyl‐substituted indene derivatives with excellent site‐selectivity and functional group compatibility.