Rhodium(III)‐Catalyzed C−H Activation of  O ‐Acetyl Ketoximes/ N ‐Methoxybenzamides toward the Synthesis of Isoquinoline/Isoquinolone‐Fused Bicycles | Zendy

Vijayan Ajesh | Zendy; Jumaila Choorappulan Ummu | Zendy; Radhakrishnan Kokkuvayil Vasu | Zendy

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Rhodium(III)‐Catalyzed C−H Activation of O ‐Acetyl Ketoximes/ N ‐Methoxybenzamides toward the Synthesis of Isoquinoline/Isoquinolone‐Fused Bicycles

Author(s) -

Vijayan Ajesh,

Jumaila Choorappulan Ummu,

Radhakrishnan Kokkuvayil Vasu

Publication year - 2017

Publication title -

asian journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.846

H-Index - 44

eISSN - 2193-5815

pISSN - 2193-5807

DOI - 10.1002/ajoc.201700377

Subject(s) - chemistry , rhodium , isoquinoline , bicyclic molecule , catalysis , medicinal chemistry , stereochemistry , combinatorial chemistry , organic chemistry

An efficient rhodium(III)‐catalyzed C−H activation approach for the construction of fused heterocyclic motifs with urea‐derived bicyclic olefins has been demonstrated. A rhodium‐catalyzed reaction of O ‐acetyl ketoximes with these bicyclic motifs furnished isoquinoline derivatives, whereas isoquinolone‐fused bicyclic olefins were obtained with the reaction of N ‐methoxybenzamides.

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