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Convenient Access to C4‐Dicarbonylation of Anilines by Iodine‐Promoted Oxidative Cross‐Coupling Reactions
Author(s) -
Wang Panpan,
Fu Yajie,
Wu Ping,
Guo Xin,
Chen Baohua
Publication year - 2017
Publication title -
asian journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.846
H-Index - 44
eISSN - 2193-5815
pISSN - 2193-5807
DOI - 10.1002/ajoc.201700212
Subject(s) - chemistry , surface modification , iodine , oxidative phosphorylation , oxidative coupling of methane , acetylene , coupling reaction , combinatorial chemistry , organic chemistry , catalysis , biochemistry
An innovative route for the construction of C4‐dicarbonylation of anilines from simple and readily available anilines and phenyl acetylene has been developed. The iodine‐promoted oxidative cross‐coupling reaction performed well and the highlight of this protocol was not N−H functionalization but C−H functionalization of unprotected anilines.