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Synthesis of Polycyclic Amides via Tandem Rh III ‐Catalyzed C−H Activation and Annulation from Dioxazolones and Alkynes
Author(s) -
Zhang GuoTai,
Dong Lin
Publication year - 2017
Publication title -
asian journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.846
H-Index - 44
eISSN - 2193-5815
pISSN - 2193-5807
DOI - 10.1002/ajoc.201700140
Subject(s) - chemistry , annulation , diphenylacetylene , tandem , catalysis , combinatorial chemistry , cascade reaction , cascade , scope (computer science) , organic chemistry , stereochemistry , medicinal chemistry , materials science , composite material , chromatography , computer science , programming language
A highly efficient synthesis of polycyclic amides by a Rh III ‐catalyzed cascade cyclization of 3‐phenyl‐1,4,2‐dioxazol‐5‐one and diphenylacetylene has been developed. This one‐pot strategy expanded the application scope of directing groups to dioxazolones.