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Highly N 2 ‐Regioselective TsOH‐Catalyzed Olefin Hydroamination: Metal‐Free Synthesis of N 2 ‐Alkyl‐1,2,3‐triazoles
Author(s) -
Wei Hao,
Hu Qingxia,
Ma Yutao,
Wei Liangming,
Liu Jiaqiang,
Shi Min,
Wang Feijun
Publication year - 2017
Publication title -
asian journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.846
H-Index - 44
eISSN - 2193-5815
pISSN - 2193-5807
DOI - 10.1002/ajoc.201700045
Subject(s) - regioselectivity , hydroamination , chemistry , olefin fiber , alkyl , catalysis , organic chemistry , combinatorial chemistry , medicinal chemistry
A highly N 2 ‐regioselective functionalization of 2 H ‐1,2,3‐triazole and 1 H ‐1,2,3‐triazole was achieved via a para ‐toluenesulfonic‐acid‐catalyzed olefin hydroamination. The reaction afforded the corresponding products with up to 92 % N 2 regioselectivity.
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