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Experimental and DFT Studies of Organocatalytic Microwave‐Assisted Reaction of Isatin Derivatives with Dinitrotoluenes
Author(s) -
Kaur Jasneet,
Islam Nasarul,
Kumar Akshay,
Chimni Swapandeep Singh
Publication year - 2017
Publication title -
asian journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.846
H-Index - 44
eISSN - 2193-5815
pISSN - 2193-5807
DOI - 10.1002/ajoc.201600614
Subject(s) - isatin , chemistry , reactivity (psychology) , microwave , organocatalysis , microwave chemistry , combinatorial chemistry , organic chemistry , reaction conditions , catalysis , computational chemistry , microwave irradiation , enantioselective synthesis , medicine , physics , alternative medicine , pathology , quantum mechanics
An organocatalytic microwave‐assisted reaction of isatin derivatives with dinitrotoluenes has been developed to provide access to variety of 3‐substituted 3‐hydroxy‐2‐oxindoles. In addition, DFT calculations were employed to understand the reactivity differences of the various nitrotoluene derivatives.