Synthesis of Tetrasubstituted Furans by Using Photoredox‐Catalyzed Coupling of 2‐Bromo‐1,3‐dicarbonyl Compounds with Silyl Enol Ethers | Zendy

Han YueYue | Zendy; Jiao YanYan | Zendy; Ren Daan | Zendy; Hu Zhentao | Zendy; Shen Sheng | Zendy; Yu Shouyun | Zendy

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Synthesis of Tetrasubstituted Furans by Using Photoredox‐Catalyzed Coupling of 2‐Bromo‐1,3‐dicarbonyl Compounds with Silyl Enol Ethers

Author(s) -

Han YueYue,

Jiao YanYan,

Ren Daan,

Hu Zhentao,

Shen Sheng,

Yu Shouyun

Publication year - 2017

Publication title -

asian journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.846

H-Index - 44

eISSN - 2193-5815

pISSN - 2193-5807

DOI - 10.1002/ajoc.201600489

Subject(s) - chemistry , enol , aromatization , silylation , photoredox catalysis , catalysis , combinatorial chemistry , organic chemistry , photocatalysis

A practical and efficient method has been developed for the preparation of polysubstituted furans by using a visible‐light‐promoted photoredox approach. The one‐pot synthesis involves a radical cyclization/deprotection/aromatization reaction sequence that proceeds smoothly under mild conditions, which makes this transformation a powerful tool for the synthesis of a variety of highly substituted furans.

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