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Rh II ‐Catalyzed Cyclization of Ester/Thioester‐Containing N ‐Sulfonyl‐1,2,3‐triazoles: Facile Synthesis of Alkylidenephthalans and Alkylidenethiophthalans
Author(s) -
Sun Run,
Jiang Yu,
Tang XiangYing,
Shi Min
Publication year - 2017
Publication title -
asian journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.846
H-Index - 44
eISSN - 2193-5815
pISSN - 2193-5807
DOI - 10.1002/ajoc.201600466
Subject(s) - chemistry , thioester , sulfonyl , catalysis , medicinal chemistry , combinatorial chemistry , organic chemistry , stereochemistry , enzyme , alkyl
A facile synthetic method has been developed to access alkylidenephthalan and alkylidenethiophthalan derivatives through the cyclization of N ‐sulfonyl‐1,2,3‐triazoles in a rhodium(II)‐catalyzed rearrangement.