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Rh III ‐Catalyzed Hydroarylation of Internal Alkynes through C−H Bond Activation
Author(s) -
Wang ChengQiang,
Feng Chao,
Loh TeckPeng
Publication year - 2016
Publication title -
asian journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.846
H-Index - 44
eISSN - 2193-5815
pISSN - 2193-5807
DOI - 10.1002/ajoc.201600144
Subject(s) - chemistry , moiety , catalysis , olefin fiber , combinatorial chemistry , medicinal chemistry , reaction conditions , stereochemistry , organic chemistry
Rh III ‐catalyzed hydroarylation of internal alkynes through C−H bond activation is described herein by using N , N ‐dimethylaminocarbonyl as a directing group without the need of an external oxidant. This protocol exhibits exceptional functionality compatibility owing to its extremely mild reaction conditions, which provides a facile and highly efficient synthetic method for olefin moiety introduction.