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Rapid Access to Triarylated Cyclotriveratrylenes from Threefold Couplings of CTV‐I 3 with Triarylbismuth Reagents
Author(s) -
Rao Maddali L. N.,
Talode Jalindar B.
Publication year - 2016
Publication title -
asian journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.846
H-Index - 44
eISSN - 2193-5815
pISSN - 2193-5807
DOI - 10.1002/ajoc.201500334
Subject(s) - chemistry , reagent , context (archaeology) , combinatorial chemistry , coupling (piping) , palladium , surface modification , catalysis , nanotechnology , organic chemistry , computational chemistry , mechanical engineering , paleontology , materials science , engineering , biology
A series of C 3 ‐symmetric triiodocyclotriveratrylene (CTV‐I 3 ) derivatives have been successfully arylated to afford the corresponding triarylcyclotriveratrylene derivatives in high yields by using triarylbismuth compounds as threefold coupling reagents under palladium‐catalyzed conditions. This functionalization is valuable in the context of the development of new synthetic and coupling studies to rapidly access cyclotriveratrylene molecular skeletons with rigid and deeper cavities.