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Total Synthesis of (+)‐Petromyroxol, a Marine Natural Product
Author(s) -
Gahalawat Suraksha,
Garg Yuvraj,
Pandey Satyendra Kumar
Publication year - 2015
Publication title -
asian journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.846
H-Index - 44
eISSN - 2193-5815
pISSN - 2193-5807
DOI - 10.1002/ajoc.201500301
Subject(s) - chemistry , total synthesis , natural product , stereoselectivity , sharpless asymmetric dihydroxylation , dihydroxylation , intramolecular force , stereochemistry , grignard reaction , enantioselective synthesis , organic chemistry , catalysis , reagent
An efficient total synthesis of (+)‐petromyroxol, a marine natural product, is described. The synthesis utilizes the Sharpless asymmetric dihydroxylation (AD), intramolecular S N 2 cyclization and stereoselective Grignard reaction as key steps.