Prins‐Driven Friedel–Crafts Reaction for the Stereoselective Synthesis of Hexahydroindeno[2,1‐ c ]pyran Derivatives | Zendy

Reddy B. V. Subba | Zendy; Reddy G. Niranjan | Zendy; Reddy M. Ramana | Zendy; Lakshmi J. K. | Zendy; Jagadeesh B. | Zendy; Sridhar B. | Zendy

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Prins‐Driven Friedel–Crafts Reaction for the Stereoselective Synthesis of Hexahydroindeno[2,1‐ c ]pyran Derivatives

Author(s) -

Reddy B. V. Subba,

Reddy G. Niranjan,

Reddy M. Ramana,

Lakshmi J. K.,

Jagadeesh B.,

Sridhar B.

Publication year - 2015

Publication title -

asian journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.846

H-Index - 44

eISSN - 2193-5815

pISSN - 2193-5807

DOI - 10.1002/ajoc.201500218

Subject(s) - chemistry , pyran , stereoselectivity , friedel–crafts reaction , domino , prins reaction , cascade reaction , cascade , stereochemistry , organic chemistry , catalysis , chromatography

A strategy has been devised for the stereoselective synthesis of hexahydroindeno[2,1‐ c ]pyran scaffolds through a domino cyclization of ( E )‐3,5‐diphenylpent‐4‐en‐1‐ol with aldehydes using BF 3 ⋅ OEt 2 at 70 °C. It is an approach for the construction of the indeno[2,1‐ c ]pyran skeleton in a one‐pot operation through a cascade cyclization.

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