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Design and Synthesis of Chiral Binaphthol‐Derived Bisphosphoric Acids and Their Application in the Catalytic Enantioselective Hydrogenation of Quinolines
Author(s) -
Wang Pei,
Jia YanE,
Zhao JiaZhen,
Zhao Dan,
Yuan Rui,
Da ChaoShan
Publication year - 2015
Publication title -
asian journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.846
H-Index - 44
eISSN - 2193-5815
pISSN - 2193-5807
DOI - 10.1002/ajoc.201500020
Subject(s) - enantioselective synthesis , chemistry , phosphonate , catalysis , organic chemistry , combinatorial chemistry , organocatalysis
A series of binaphthol‐based bisphosphoric acids were successfully developed with inclusion of rigid cyclic phosphamide and phosphonate motifs. These chiral bisphosphoric acids were used as chiral organocatalysts in the hydrogen transformation of a series of quinolines to investigate their enantioselective catalytic activity.