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Fast and Complete Transimination of NH Imines into O ‐Alkyl Oximes
Author(s) -
Jeon Mina,
Gupta Sreya,
Im YoungWoong,
Rhee Young Ho,
Park Jaiwook
Publication year - 2015
Publication title -
asian journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.846
H-Index - 44
eISSN - 2193-5815
pISSN - 2193-5807
DOI - 10.1002/ajoc.201402293
Subject(s) - chemistry , alkyl , hydroxylamine , organic chemistry , medicinal chemistry , transformation (genetics) , biochemistry , gene
A synthetic method for making O ‐alkyl oximes was developed by combining the Ru‐catalyzed transformation of alkyl azides into NH imines and a transimination reaction with O ‐alkyl hydroxylamine hydrochlorides. This process provides a wide range of O ‐alkyl oximes in high yields at room temperature in short reaction times.