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Microwave‐Assisted Construction of C ‐Hydroxydiketopiperazines using Lanthanum(III) Triflate
Author(s) -
Wang QingPeng,
Zhang HongBo,
Ning Xin,
Hang Hang,
Huang ZhongLv,
Song HaoRan,
Wang Xin,
Wang Peng George
Publication year - 2015
Publication title -
asian journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.846
H-Index - 44
eISSN - 2193-5815
pISSN - 2193-5807
DOI - 10.1002/ajoc.201402277
Subject(s) - lanthanum , chemistry , trifluoromethanesulfonate , reagent , substrate (aquarium) , microwave chemistry , microwave , epimer , inorganic chemistry , combinatorial chemistry , organic chemistry , catalysis , microwave irradiation , oceanography , physics , quantum mechanics , geology
A highly efficient and convenient method for the construction of C ‐hydroxydiketopiperazines has been developed using Lanthanum(III) triflate as a recyclable reagent. Microwave heating dramatically enhances the reaction rate without the epimerization of the existing chiral center in the substrate.