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Palladium‐Catalyzed Desulfinative Iodination of Sodium Sulfinates and Sulfonyl Hydrazides
Author(s) -
Liu Saiwen,
Chen Jinjin,
Zhang Ran,
Zhao Feng,
Deng GuoJun
Publication year - 2014
Publication title -
asian journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.846
H-Index - 44
eISSN - 2193-5815
pISSN - 2193-5807
DOI - 10.1002/ajoc.201402140
Subject(s) - chemistry , sulfonyl , halogenation , palladium , catalysis , sodium , sodium salt , organic chemistry , inorganic chemistry , alkyl
The palladium‐catalyzed desulfinative iodination of sodium sulfinates and sulfonyl hydrazides with KI or I 2 is described. The reaction proceeds smoothly under mild conditions using O 2 or air as an environmentally benign oxidant.