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Cover Picture: Synthesis and Optical Properties of Tetraaryl‐1,4‐dihydropyrrolo[3,2‐ b ]pyrroles (Asian J. Org. Chem. 5/2013)
Author(s) -
Janiga Anita,
GlodkowskaMrowka Eliza,
Stoklosa Tomasz,
Gryko Daniel T.
Publication year - 2013
Publication title -
asian journal of organic chemistry
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 0.846
H-Index - 44
eISSN - 2193-5815
pISSN - 2193-5807
DOI - 10.1002/ajoc.201390012
Subject(s) - chemistry , domino , butane , cover (algebra) , fluorescence , combinatorial chemistry , polymer chemistry , organic chemistry , catalysis , optics , mechanical engineering , physics , engineering
Six bonds are formed on one pot to give 1,4‐dihydropyrrole[3,2‐b]pyrroles in an operationally simple reaction that is described by Daniel Gryko and co‐workers in their Full Paper on page 411 ff. The target compounds are formed in a domino process from aldehydes, primary amines, and butane‐2,3‐dione. Such fused pyrroles have interesting optical properties but are among the least studied heteropentalenes because they have previously been difficult to synthesize. One of several potential applications of 1,4‐dihydropyrrole[3,2‐ b ]pyrroles is demonstrated in a fluorescent cell‐imaging experiment.

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