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Rapid, Sustainable, and Gram‐Scale Synthesis of Phenols Catalyzed by a Biodegradable Deep Eutectic Mixture in Water
Author(s) -
Wang Liang,
Dai DongYan,
Chen Qun,
He MingYang
Publication year - 2013
Publication title -
asian journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.846
H-Index - 44
eISSN - 2193-5815
pISSN - 2193-5807
DOI - 10.1002/ajoc.201300192
Subject(s) - deep eutectic solvent , choline chloride , chemistry , yield (engineering) , phenols , catalysis , eutectic system , organic chemistry , scale (ratio) , gram , urea , solvent , combinatorial chemistry , bacteria , materials science , physics , alloy , quantum mechanics , metallurgy , biology , genetics
In deep : A rapid, sustainable, and gram‐scale synthesis of phenols from aryl/heteroarylboronic acids and their derivatives in the presence of a deep eutectic solvent (DES) of choline chloride and urea has been developed. The reactions proceed at room temperature to give the desired products selectively in a few minutes and the catalyst is recyclable up to five times without loss of product yield.