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Copper‐Catalyzed Electrochemical Chlorination of 1,3‐Dicarbonyl Compounds Using Hydrochloric Acid
Author(s) -
Tsuchida Kazuya,
Kochi Takuya,
Kakiuchi Fumitoshi
Publication year - 2013
Publication title -
asian journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.846
H-Index - 44
eISSN - 2193-5815
pISSN - 2193-5807
DOI - 10.1002/ajoc.201300168
Subject(s) - chemistry , hydrochloric acid , chlorine , reagent , electrochemistry , catalysis , copper , solvent , combinatorial chemistry , organic chemistry , inorganic chemistry , electrode
Electric avenue : A copper‐catalyzed electrochemical α‐chlorination of 1,3‐dicarbonyl compounds using hydrochloric acid as a chlorine source is described. Monochlorination products can be obtained from various 1,3‐dicarbonyl compounds by using a reaction system where the only required reagents are a substrate, a solvent, a copper(II) salt and hydrochloric acid.