Specific Enhancement of Reactivity and Selectivity in the Substitution Reactions of Polyhydroxy Derivatives by Lithium Chloride | Zendy

Watanabe Yutaka | Zendy; Kawamoto Mao | Zendy; Shintaku Hiroyuki | Zendy; Tanabe Kae | Zendy; Ohta Hidetoshi | Zendy; Hayashi Minoru | Zendy

Premium

Specific Enhancement of Reactivity and Selectivity in the Substitution Reactions of Polyhydroxy Derivatives by Lithium Chloride

Author(s) -

Watanabe Yutaka,

Kawamoto Mao,

Shintaku Hiroyuki,

Tanabe Kae,

Ohta Hidetoshi,

Hayashi Minoru

Publication year - 2013

Publication title -

asian journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.846

H-Index - 44

eISSN - 2193-5815

pISSN - 2193-5807

DOI - 10.1002/ajoc.201300163

Subject(s) - chemistry , selectivity , diol , intramolecular force , reactivity (psychology) , lithium (medication) , vicinal , hydrogen bond , substitution (logic) , organic chemistry , lithium chloride , substitution reaction , chloride , electrophilic aromatic substitution , medicinal chemistry , catalysis , molecule , medicine , alternative medicine , pathology , computer science , programming language , endocrinology

Diol A for activation: LiCl mediates mono‐ O ‐substitution of vicinal diol derivatives that are capable of forming intramolecular hydrogen bonds. The remarkable selectivity that leads to mono‐ O ‐substitution was demonstrated in polyols such as cyclitols and saccharides. SM=starting material.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research