Oxidative Aromatic CH Functionalization Promoted by Phenyliodine(III) Diacetate to form CN, CS, and CSe Bonds | Zendy

Kumar Rapolu Kiran | Zendy; Manna Sudeshna | Zendy; Mahesh Devulapally | Zendy; Sar Dinabandhu | Zendy; Punniyamurthy Tharmalingam | Zendy

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Oxidative Aromatic CH Functionalization Promoted by Phenyliodine(III) Diacetate to form CN, CS, and CSe Bonds

Author(s) -

Kumar Rapolu Kiran,

Manna Sudeshna,

Mahesh Devulapally,

Sar Dinabandhu,

Punniyamurthy Tharmalingam

Publication year - 2013

Publication title -

asian journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.846

H-Index - 44

eISSN - 2193-5815

pISSN - 2193-5807

DOI - 10.1002/ajoc.201300151

Subject(s) - chemistry , trifluoroacetic acid , surface modification , benzimidazole , medicinal chemistry , oxidative phosphorylation , aryl , stereochemistry , combinatorial chemistry , organic chemistry , biochemistry , alkyl

Se what I mean? Metal‐free oxidative syntheses of benzo[ d ]imidazo[2,1‐ b ]benzo‐thiazoles, benzimidazole‐2‐thiones, N ‐aryl benzimidazoles, and benzo[ d ]imidazo[2,1‐ b ]benzoselenozoles are described. CN, CS, and CSe bonds are formed from by aromatic CH functionalization promoted by phenyliodine(III) diacetate. EDG=electron‐withdrawing group; EWG=electron‐donating group; HFIP=1,1,1,3,3,3,‐hexafluoro‐2‐propanol; TFA=trifluoroacetic acid.

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