Rhodium‐Catalyzed Synthesis and Reactions of  N ‐Acylphthalimides | Zendy

Li Guangzhe | Zendy; Arisawa Mieko | Zendy; Yamaguchi Masahiko | Zendy

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Rhodium‐Catalyzed Synthesis and Reactions of N ‐Acylphthalimides

Author(s) -

Li Guangzhe,

Arisawa Mieko,

Yamaguchi Masahiko

Publication year - 2013

Publication title -

asian journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.846

H-Index - 44

eISSN - 2193-5815

pISSN - 2193-5807

DOI - 10.1002/ajoc.201300094

Subject(s) - phthalimides , chemistry , rhodium , catalysis , medicinal chemistry , benzene , cleavage (geology) , organic chemistry , phthalimide , geotechnical engineering , fracture (geology) , engineering

A complex of [RhH(PPh 3 ) 4 ] and 1,2‐bis(diphenylphosphino)benzene (dppBz) catalyzes the syntheses and reactions of N ‐acylphthalimides. N ‐Acylphthalimides were synthesized by the imidation of thioesters or acid fluorides by N ‐(organothio)phthalimides. CN bond cleavage in N ‐acylphthalimides was also catalyzed by the same rhodium complex. Thioesters and N ‐(phosphinoyl)phthalimides were obtained from reactions with phosphinothioates; acid fluorides and N ‐(tetrafluoroaryl)phthalimides were obtained from reactions with substituted pentafluorobenzenes.

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