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Negative Solvatochromism of an Anionic Thiazole‐Based Dye
Author(s) -
Schade Alexander,
Menzel Roberto,
Görls Helmar,
Spange Stefan,
Beckert Rainer
Publication year - 2013
Publication title -
asian journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.846
H-Index - 44
eISSN - 2193-5815
pISSN - 2193-5807
DOI - 10.1002/ajoc.201300085
Subject(s) - solvatochromism , chemistry , chromophore , thiazole , combinatorial chemistry , computational chemistry , photochemistry , stereochemistry , organic chemistry , molecule
Keep it small, flat, and easy : The synthesis of an unconventional strong solvatochromic dye is presented. The solvatochromic and NMR behavior of the anionic chromophore was characterized and the compound might be used as a sensor. The thiazol‐4‐olate donor group is derived from the oxyluciferin of fireflies and strongly influences the electronic properties of the dye.

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