Preparation of a Spontaneously Resolved Chiral Fluorescent System Containing 4‐(2‐Arylethynyl)benzoic Acid | Zendy

Taniguchi Naoya | Zendy; Shimomaki Ryutaro | Zendy; Amako Tomoyuki | Zendy; Sato Tomohiro | Zendy; Tokutome Hayato | Zendy; Tajima Nobuo | Zendy; Kuroda Reiko | Zendy; Fujiki Michiya | Zendy; Imai Yoshitane | Zendy

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Preparation of a Spontaneously Resolved Chiral Fluorescent System Containing 4‐(2‐Arylethynyl)benzoic Acid

Author(s) -

Taniguchi Naoya,

Shimomaki Ryutaro,

Amako Tomoyuki,

Sato Tomohiro,

Tokutome Hayato,

Tajima Nobuo,

Kuroda Reiko,

Fujiki Michiya,

Imai Yoshitane

Publication year - 2013

Publication title -

asian journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.846

H-Index - 44

eISSN - 2193-5815

pISSN - 2193-5807

DOI - 10.1002/ajoc.201300084

Subject(s) - chemistry , fluorescence , fluorophore , benzoic acid , luminescence , molecule , solid state , chirality (physics) , organic chemistry , photochemistry , combinatorial chemistry , optics , physics , chiral symmetry breaking , quantum mechanics , nambu–jona lasinio model , quark

A spontaneously resolved chiral fluorescent system was prepared from achiral 4‐(2‐arylethynyl)benzoic acid and racemic ( rac )‐1‐phenylethylamine. Although functional chiral organic materials are usually prepared from chiral molecules, the chiral organic fluorophore described herein is successfully generated from achiral and racemic molecules to form a system that emits circularly polarized luminescence (CPL) in the solid state.

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