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Palladium‐catalyzed Asymmetric 1,4‐Addition of Diarylphosphines to α,β‐Unsaturated Carboxylic Esters
Author(s) -
Du Dan,
Lin ZiQi,
Lu JunZhu,
Li Chun,
Duan WeiLiang
Publication year - 2013
Publication title -
asian journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.846
H-Index - 44
eISSN - 2193-5815
pISSN - 2193-5807
DOI - 10.1002/ajoc.201300021
Subject(s) - chemistry , pincer movement , palladium , stereoselectivity , catalysis , enantioselective synthesis , carboxylic acid , organic chemistry , medicinal chemistry
Pincer my ride : A highly stereoselective asymmetric 1,4‐addition of diarylphosphines to α,β‐unsaturated carboxylic esters catalyzed by a PCP pincer–Pd complex has been developed for the synthesis of chiral phosphines in up to 99 % ee.
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