Redox Potential of Nitroxides is an Index to Evaluate Superoxide Dismutase Mimic Activity | Zendy

Yamasaki Toshihide | Zendy; Matsuoka Yuta | Zendy; Mito Fumiya | Zendy; Yamato Mayumi | Zendy; Yamada Kenichi | Zendy

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Redox Potential of Nitroxides is an Index to Evaluate Superoxide Dismutase Mimic Activity

Author(s) -

Yamasaki Toshihide,

Matsuoka Yuta,

Mito Fumiya,

Yamato Mayumi,

Yamada Kenichi

Publication year - 2013

Publication title -

asian journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.846

H-Index - 44

eISSN - 2193-5815

pISSN - 2193-5807

DOI - 10.1002/ajoc.201300011

Subject(s) - chemistry , nitroxide mediated radical polymerization , superoxide dismutase , redox , superoxide , piperidine , reactivity (psychology) , combinatorial chemistry , biochemistry , stereochemistry , enzyme , organic chemistry , medicine , alternative medicine , radical polymerization , pathology , copolymer , polymer

Superoxide dismutase it : The structure‐reactivity relationship of piperidine nitroxides modified at the C4 position against superoxide was evaluated. The redox potential of nitroxides and N ‐oxoammonium cation couples correlates strongly with their reactivity toward superoxide. Thus, the superoxide dismutase activity of a nitroxide can be controlled based on its redox potential.

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